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Acquiring Scientific Information in the 21st Century1 Joan Selverstone Valentine pp 1–1 DOI: 10.1021/ar990151a |
Soluble Molybdenum Blues “des Pudels Kern”Achim Müller and Claire Serain pp 2–10 DOI: 10.1021/ar9601510 |
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Glycosidase Mechanisms: Anatomy of a Finely Tuned Catalyst David L. Zechel and Stephen G. Withers pp 11–18 DOI: 10.1021/ar970172+ |
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Transition States for Surface-Catalyzed Chemistry Andrew J. Gellman* pp 19–26 DOI: 10.1021/ar970118t |
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Monolayer-Protected Cluster Molecules Allen C. Templeton, W. Peter Wuelfing, and Royce W. Murray pp 27–36 DOI: 10.1021/ar9602664 |
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Nanoshocks in Molecular Materials Dana D. Dlott pp 37–45 DOI: 10.1021/ar970260u |
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Synthesis and Reactivities of Cubane-Type Sulfido Clusters Containing Noble Metals Masanobu Hidai and Shigeki Kuwata, Yasushi Mizobe pp 46–52 DOI: 10.1021/ar990016y |
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One-Dimensional Polymers and Mesogens Incorporating Multiple Bonds between Metal Atoms Malcolm H. Chisholm pp 53–61 DOI: 10.1021/ar9800901 |
Issue 02
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Molecule Liftoff from Surfaces Barbara J. Garrison and Arnaud Delcorte, Kristin D. Krantzman pp 69–77 DOI: 10.1021/ar970135i |
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Hybrid Electrochemical/Chemical Synthesis of Quantum Dots Reginald M. Penner pp 78–86 DOI: 10.1021/ar9702839 |
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What Controls the Rates of Interprotein Electron-Transfer Reactions Victor L. Davidson pp 87–93 DOI: 10.1021/ar9900616 |
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Biomaterials in Drug Delivery and Tissue Engineering: One Laboratory's Experience Robert Langer pp 94–101 DOI: 10.1021/ar9800993 |
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Organic Synthesis and Chemical Ecology Kenji Mori pp 102–110 DOI: 10.1021/ar990006x |
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Femtosecond Studies of Electron Dynamics at Interfaces Nien-Hui Ge, Chung M. Wong, and Charles B. Harris pp 111–118 DOI: 10.1021/ar980138a |
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What Do Titano- and Zirconocenes Do with Diynes and Polyynes? Uwe Rosenthal, Paul-Michael Pellny, Frank G. Kirchbauer, and Vladimir V. Burlakov pp 119–129 DOI: 10.1021/ar9900109 |
Issue 03
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Doped Rare Gas Solids as Model Systems for Chromophore−Matrix Interactions Peter Geissinger, Thomas Giering, Wolfgang Richter, and Dietrich Haarer pp 131–138 DOI: 10.1021/ar980011l |
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Two-State Reactivity as a New Concept in Organometallic Chemistry Detlef Schröder, Sason Shaik, and Helmut Schwarz pp 139–145 DOI: 10.1021/ar990028j |
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Oligothienylenevinylenes as a New Class of Multinanometer Linear π-Conjugated Systems for Micro- and Nanoelectronics Jean Roncali pp 147–156 DOI: 10.1021/ar990023m |
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Recovery of Carbonyl Compounds from N,N-Dialkylhydrazones Dieter Enders, Lars Wortmann, and René Peters pp 157–169 DOI: 10.1021/ar990062y |
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Catalytic Macrocyclizations of Thietanes and Thiiranes by Metal Carbonyl Complexes Richard D. Adams pp 171–178 DOI: 10.1021/ar980092l |
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Mass Spectrometry in Viral Proteomics Ray Bakhtiar, and John J. Thomas, Gary Siuzdak pp 179–187 DOI: 10.1021/ar9801200 |
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Crystal and Molecular Simulation of High-Performance Polymers Howard M. Colquhoun and David J. Williams pp 189–198 DOI: 10.1021/ar980123c |
Issue 04
Molecular Tennis Flat Smashes and Wicked CutsAndrew J. Alexander and Richard N. Zare pp 199–205 DOI: 10.1021/ar970297e |
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High-Pressure Pulse Radiolysis as a Tool in the Study of Transition Metal Reaction Mechanisms Rudi van Eldik and Dan Meyerstein pp 207–214 DOI: 10.1021/ar990067v |
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Synthesis of Diverse and Complex Molecules on the Solid Phase Sebastian Wendeborn, Alain De Mesmaeker, Wolfgang K.-D. Brill, and Sabine Berteina pp 215–224 DOI: 10.1021/ar990100d |
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Low-Valent Ruthenium and Iridium Hydride Complexes as Alternatives to Lewis Acid and Base Catalysts Shun-Ichi Murahashi and Hikaru Takaya pp 225–233 DOI: 10.1021/ar980085x |
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Design of Luminescent Inorganic Materials: New Photophysical Processes Studied by Optical Spectroscopy Daniel R. Gamelin and Hans U. Güdel pp 235–242 DOI: 10.1021/ar990102y |
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Mechanistic Aspects of β-Bond-Cleavage Reactions of Aromatic Radical Cations Enrico Baciocchi, Massimo Bietti, and Osvaldo Lanzalunga pp 243–251 DOI: 10.1021/ar980014y |
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Long-Range Charge Transfer in DNA: Transient Structural Distortions Control the Distance Dependence Gary B. Schuster pp 253–260 DOI: 10.1021/ar980059z |
Issue 05
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Reaction Kinetics at Very Low Temperatures: Laboratory Studies and Interstellar Chemistry Ian W. M. Smith and Bertrand R. Rowe pp 261–268 DOI: 10.1021/ar990099i |
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Molecular Photovoltaics Anders Hagfeldt and Michael Grätzel pp 269–277 DOI: 10.1021/ar980112j |
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Stereoelectronic Control in Diels−Alder Reaction of Dissymmetric 1,3-Dienes Goverdhan Mehta and R. Uma pp 278–286 DOI: 10.1021/ar990123s |
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Electron and Proton Reservoir Complexes: Thermodynamic Basis for C−H Activation and Applications in Redox and Dendrimer Chemistry Didier Astruc pp 287–298 DOI: 10.1021/ar9901319 |
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Identification of Peptide Oxidation by Tandem Mass Spectrometry Kevin L. Schey and Eric L. Finley pp 299–306 DOI: 10.1021/ar9800744 |
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Spectroscopic and Dynamic Studies of the Epidermal Chromophores trans-Urocanic Acid and Eumelanin John D. Simon pp 307–313 DOI: 10.1021/ar970250t |
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Anionic Pd(0) and Pd(II) Intermediates in Palladium-Catalyzed Heck and Cross-Coupling Reactions Christian Amatore and Anny Jutand pp 314–321 DOI: 10.1021/ar980063a |
Issue 06
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Catalytic Asymmetric Synthesis Special Issue Christopher S. Foote pp 323–323 DOI: 10.1021/ar0000455 |
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Catalytic Asymmetric Synthesis Scott E. Denmark, Eric N. Jacobsen pp 324–324 DOI: 10.1021/ar000046x |
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Chiral Bis(oxazoline) Copper(II) Complexes: Versatile Catalysts for Enantioselective Cycloaddition, Aldol, Michael, and Carbonyl Ene Reactions Jeffrey S. Johnson and David A. Evans pp 325–335 DOI: 10.1021/ar960062n |
Phosphinooxazolines A New Class of Versatile, Modular P,N-Ligands for Asymmetric CatalysisGünter Helmchen and Andreas Pfaltz pp 336–345 DOI: 10.1021/ar9900865 |
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Phosphoramidites: Marvellous Ligands in Catalytic Asymmetric Conjugate Addition Ben L. Feringa pp 346–353 DOI: 10.1021/ar990084k |
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Chiral Monodentate Phosphine Ligand MOP for Transition-Metal-Catalyzed Asymmetric Reactions Tamio Hayashi pp 354–362 DOI: 10.1021/ar990080f |
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Modular Phospholane Ligands in Asymmetric Catalysis Mark J. Burk pp 363–372 DOI: 10.1021/ar990085c |
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The Discovery of Novel Reactivity in the Development of C−C Bond-Forming Reactions: In Situ Generation of Zinc Acetylides with ZnII/R3N D. E. Frantz, R. Fässler, C. S. Tomooka, and E. M. Carreira pp 373–381 DOI: 10.1021/ar990078o |
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Enantioselective Automultiplication of Chiral Molecules by Asymmetric Autocatalysis Kenso Soai, Takanori Shibata, and Itaru Sato pp 382–390 DOI: 10.1021/ar9900820 |
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Enantiomer-Selective Activation of Racemic Catalysts Koichi Mikami, Masahiro Terada, Toshinobu Korenaga, Yousuke Matsumoto, and Satoru Matsukawa pp 391–401 DOI: 10.1021/ar9900818 |
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Kinetic Aspects of Nonlinear Effects in Asymmetric Catalysis Donna G. Blackmond pp 402–411 DOI: 10.1021/ar990083s |
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Enantioselective Nucleophilic Catalysis with “Planar-Chiral” Heterocycles Gregory C. Fu pp 412–420 DOI: 10.1021/ar990077w |
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Asymmetric Catalysis of Epoxide Ring-Opening Reactions Eric N. Jacobsen pp 421–431 DOI: 10.1021/ar960061v |
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Asymmetric Catalysis of Aldol Reactions with Chiral Lewis Bases Scott E. Denmark and Robert A. Stavenger pp 432–440 DOI: 10.1021/ar960027g |
Issue 07
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H-Densities: A New Concept for Hydrated Molecules David C. Clary, David M. Benoit, and Tanja van Mourik pp 441–447 DOI: 10.1021/ar9800643 |
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Hypersensitive Radical Probes and the Mechanisms of Cytochrome P450-Catalyzed Hydroxylation Reactions Martin Newcomb and Patrick H. Toy pp 449–455 DOI: 10.1021/ar960058b |
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Nanofabrication of Self-Assembled Monolayers Using Scanning Probe Lithography Gang-Yu Liu, Song Xu, and Yile Qian pp 457–466 DOI: 10.1021/ar980081s |
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Nickel-Catalyzed Cyclizations, Couplings, and Cycloadditions Involving Three Reactive Components John Montgomery pp 467–473 DOI: 10.1021/ar990095d |
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A Dynamic View of Self-Assembled Monolayers Antonella Badia, R. Bruce Lennox, and Linda Reven pp 475–481 DOI: 10.1021/ar9702841 |
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The Whole Story of the Two-Electron Bond, with the δ Bond as a Paradigm F. Albert Cotton and Daniel G. Nocera pp 483–490 DOI: 10.1021/ar980116o |
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Raising Flags: Applications of Chemical Marker Groups To Study Self-Assembly, Chirality, and Orientation of Interfacial Films by Scanning Tunneling Microscopy Leanna C. Giancarlo and George W. Flynn pp 491–501 DOI: 10.1021/ar970261m |
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Elucidating a Biological Role for Chromium at a Molecular Level John B. Vincent pp 503–510 DOI: 10.1021/ar990073r |
Issue 08
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Nickel-Catalyzed Intermolecular Domino Reactions Shin-ichi Ikeda pp 511–519 DOI: 10.1021/ar9901016 |
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Scanning Tunneling Microscopy: A Unique Tool in the Study of Chirality, Dynamics, and Reactivity in Physisorbed Organic Monolayers Steven De Feyter, André Gesquière, Mohamed M. Abdel-Mottaleb, Petrus C. M. Grim, and Frans C. De Schryver, Christian Meiners, Michel Sieffert, Suresh Valiyaveettil, and Klaus Müllen pp 520–531 DOI: 10.1021/ar970040g |
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Crystallographic Structure Determination of Unstable Species Ilme Schlichting pp 532–538 DOI: 10.1021/ar9900459 |
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Co(III)−Alkylperoxo Complexes: Syntheses, Structure−Reactivity Correlations, and Use in the Oxidation of Hydrocarbons Ferman A. Chavez and Pradip K. Mascharak pp 539–545 DOI: 10.1021/ar990089h |
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Soluble Polymer-Supported Organic Synthesis Patrick H. Toy and Kim D. Janda pp 546–554 DOI: 10.1021/ar990140h |
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Atomistic Modeling of Enantioselective Binding Kenny B. Lipkowitz pp 555–562 DOI: 10.1021/ar980115w |
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Laser Photochemistry of Molecular Oxygen David H. Parker pp 563–571 DOI: 10.1021/ar980012d |
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Optimal Control of Molecular Motion: Design, Implementation, and Inversion Herschel Rabitz and Wusheng Zhu pp 572–578 DOI: 10.1021/ar990054h |
Issue 09
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Covalent Inhibition of Digestive Lipases by Chiral Phosphonates Jean-François Cavalier and Gerard Buono Robert Verger, pp 579–589 DOI: 10.1021/ar990150i |
Nucleic Acid Aptamers From Selection in Vitro to Applications in VivoMichael Famulok, Günter Mayer, and Michael Blind pp 591–599 DOI: 10.1021/ar960167q |
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Intermolecular Interactions in Nonorganic Crystal Engineering Dario Braga, Fabrizia Grepioni pp 601–608 DOI: 10.1021/ar990143u |
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Selectivity in Proton Transfer, Hydrogen Bonding, and Solvation Alessandro Bagno and Gianfranco Scorrano pp 609–616 DOI: 10.1021/ar990149j |
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Cycloaddition Chemistry of Organic Molecules with Semiconductor Surfaces Robert J. Hamers, Sarah K. Coulter, Mark D. Ellison, Jennifer S. Hovis, David F. Padowitz, and Michael P. Schwartz, C. Michael Greenlief, John N. Russell, Jr. pp 617–624 DOI: 10.1021/ar970281o |
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Heavy Ketones, the Heavier Element Congeners of a Ketone Renji Okazaki and Norihiro Tokitoh pp 625–630 DOI: 10.1021/ar980073b |
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Long-Distance Charge Transport in DNA: The Hopping Mechanism Bernd Giese pp 631–636 DOI: 10.1021/ar990040b |
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From Boiling Stones to Smart Crystals: Supramolecular and Magnetic Isotope Control of Radical−Radical Reactions in Zeolites Nicholas J. Turro pp 637–646 DOI: 10.1021/ar980103a |
Issue 10
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Chemistry and Physics of Supramolecular Magnetic Materials Olivier Kahn pp 647–657 DOI: 10.1021/ar9703138 |
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Do Secondary Orbital Interactions Really Exist? José I. García, José A. Mayoral, and Luis Salvatella pp 658–664 DOI: 10.1021/ar0000152 |
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Luminescent Photoproducts in UV-Irradiated Ice Vaughan S. Langford, Allan J. McKinley, and Terence I. Quickenden pp 665–671 DOI: 10.1021/ar990145e |
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Metal Ion Effects in Isotopic Hydrogen Exchange in Biologically Important Heterocycles Erwin Buncel and Omoshile Clement, Ikenna Onyido pp 672–678 DOI: 10.1021/ar970209q |
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Stereocontrol in Cyclophane Synthesis: A Photochemical Method To Overlap Aromatic Rings Jun Nishimura, Yosuke Nakamura, Yoshitou Hayashida, and Takako Kudo pp 679–686 DOI: 10.1021/ar9901422 |
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Is the Translational Diffusion of Organic Radicals Different from That of Closed-Shell Molecules? Masahide Terazima pp 687–694 DOI: 10.1021/ar000003g |
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Excited-State Properties of C60 Fullerene Derivatives Dirk M. Guldi, Maurizio Prato pp 695–703 DOI: 10.1021/ar990144m |
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Stable Silylenes Michael Haaf, Thomas A. Schmedake, and Robert West pp 704–714 DOI: 10.1021/ar950192g |
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Dynamic Thermodynamic Resolution: Control of Enantioselectivity through Diastereomeric Equilibration Peter Beak, David R. Anderson, Michael D. Curtis, Jason M. Laumer, Daniel J. Pippel, and Gerald A. Weisenburger pp 715–727 DOI: 10.1021/ar000077s |
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Metal Coordination and Mechanism of Multicopper Nitrite Reductase Shinnichiro Suzuki, Kunishige Kataoka, and Kazuya Yamaguchi pp 728–735 DOI: 10.1021/ar9900257 |
Issue 11
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Electrocatalysis and Charge-Transfer Reactions at Redox-Modified Zeolites Debra R. Rolison, Carol A. Bessel pp 737–744 DOI: 10.1021/ar9701272 |
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De Novo Design of Helical Bundles as Models for Understanding Protein Folding and Function R. Blake Hill, Daniel P. Raleigh, Angela Lombardi, and William F. DeGrado pp 745–754 DOI: 10.1021/ar970004h |
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Exploration of Mixed-Valence Chemistry: Inventing New Analogues of the Creutz-Taube Ion Wolfgang Kaim, Axel Klein, and Markus Glöckle pp 755–763 DOI: 10.1021/ar960067k |
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The Interplay of Theory and Experiment in the Study of Phenylnitrene Weston Thatcher Borden, Nina P. Gritsan, Christopher M. Hadad, William L. Karney, Carl R. Kemnitz, and Matthew S. Platz pp 765–771 DOI: 10.1021/ar990030a |
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Lead Salt Quantum Dots: the Limit of Strong Quantum Confinement Frank W. Wise pp 773–780 DOI: 10.1021/ar970220q |
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Measurement of Orientation in Organic Thin Films Garth J. Simpson and Kathy L. Rowlen pp 781–789 DOI: 10.1021/ar0000307 |
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Molecular Electronics. Synthesis and Testing of Components James M. Tour pp 791–804 DOI: 10.1021/ar0000612 |
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Oxidative Folding of Proteins Mahesh Narayan, Ervin Welker, William J. Wedemeyer, and Harold A. Scheraga pp 805–812 DOI: 10.1021/ar000063m |
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Development of Reactions of Silacyclopropanes as New Methods for Stereoselective Organic Synthesis Annaliese K. Franz and K. A. Woerpel pp 813–820 DOI: 10.1021/ar9900562 |
Issue 12
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Conformations of Linear Chains. Systematics and Suggestions for Nomenclature Josef Michl, Robert West pp 821–823 DOI: 10.1021/ar0001057 |
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Radical−Water Complexes in Earth's Atmosphere Simone Aloisio and Joseph S. Francisco pp 825–830 DOI: 10.1021/ar000097u |
Calamitics, Cubics, and Columnars Liquid-Crystalline Complexes of Silver(I)Duncan W. Bruce pp 831–840 DOI: 10.1021/ar990159k |
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Fabrication inside Microchannels Using Fluid Flow Paul J. A. Kenis, Rustem F. Ismagilov, Shuichi Takayama, and George M. Whitesides, Shulong Li and Henry S. White pp 841–847 DOI: 10.1021/ar000062u |
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Synthetic Catalysis of Amide Isomerization Christopher Cox and Thomas Lectka pp 849–858 DOI: 10.1021/ar990165g |
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Ligand K-Edge X-ray Absorption Spectroscopy: A Direct Probe of Ligand−Metal Covalency Thorsten Glaser, Britt Hedman, Keith O. Hodgson, and Edward I. Solomon pp 859–868 DOI: 10.1021/ar990125c |
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Additive Fabrication and the Mechanisms of Nucleation and Growth in Chemical Vapor Deposition Processes Elizabeth L. Crane, Gregory S. Girolami, and Ralph G. Nuzzo pp 869–877 DOI: 10.1021/ar960102n |
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Recent Advances in the Biginelli Dihydropyrimidine Synthesis. New Tricks from an Old Dog C. Oliver Kappe pp 879–888 DOI: 10.1021/ar000048h |
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Calculating Structures and Free Energies of Complex Molecules: Combining Molecular Mechanics and Continuum Models Peter A. Kollman, Irina Massova, Carolina Reyes, Bernd Kuhn, Shuanghong Huo, Lillian Chong, Matthew Lee, Taisung Lee, Yong Duan, Wei Wang, Oreola Donini, Piotr Cieplak, Jaysharee Srinivasan, David A. Case, and Thomas E. Cheatham, III pp 889–897 DOI: 10.1021/ar000033j |